P. Ko?ovský and J. Bäckvall, -Dichotomy in the Palladium-Catalyzed Addition of Nucleophiles to Alkenes, Chemistry - A European Journal, vol.124, issue.83, p.36, 2015.
DOI : 10.1002/chem.201404070

R. I. Mcdonald, G. Liu, and S. S. Stahl, Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications, Chemical Reviews, vol.111, issue.4, p.2981, 2011.
DOI : 10.1021/cr100371y

J. A. Keith and P. M. Henry, The Mechanism of the Wacker Reaction: A Tale of Two Hydroxypalladations, Angewandte Chemie International Edition, vol.903, issue.48, p.9038, 2009.
DOI : 10.1002/anie.200902194

A. Minatti and K. Muñiz, Intramolecular aminopalladation of alkenes as a key step to pyrrolidines and related heterocycles, Chem. Soc. Rev., vol.127, issue.7, p.1142, 2007.
DOI : 10.1039/B607474J

E. M. Beccalli, G. Broggini, M. Martinelli, and S. Sottocornola, Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents, Chemical Reviews, vol.107, issue.11, p.5318, 2007.
DOI : 10.1021/cr068006f

S. Cacchi and A. , Arcadi. in Handbook of Organopalladium Chemistry for Organic Synthesis, p.2289, 2002.

T. Jensen and P. Fristrup, Toward Efficient Palladium-Catalyzed Allylic C???H Alkylation, Chemistry - A European Journal, vol.130, issue.259, p.9632, 2009.
DOI : 10.1002/chem.200901935

T. A. Ramirez, B. Zhao, and Y. Shi, C???H amination adjacent to double bonds and carbonyl groups, Chem. Soc. Rev., vol.74, issue.2, p.931, 2012.
DOI : 10.1039/C1CS15104E

C. J. Engelin and P. Fristrup, Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective, Molecules, vol.16, issue.12, p.951, 2011.
DOI : 10.3390/molecules16010951

T. Dang, I. Abdellah, Y. Canac, and R. Chauvin, Intramolecular CH Oxidative N-Allylation of C-Homoallylhydrazones to 5-Vinyl-2-pyrazolines Catalyzed by the [Pd(OAc)2]/BIMINAP System, ChemCatChem, vol.44, issue.9, p.1491, 2011.
DOI : 10.1002/cctc.201100108

P. Sehnal, R. J. Taylor, and I. J. Fairlamb, Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis, Chemical Reviews, vol.110, issue.2, p.824, 2010.
DOI : 10.1021/cr9003242

T. W. Lyons and M. S. Sanford, Palladium-Catalyzed Ligand-Directed C???H Functionalization Reactions, Chemical Reviews, vol.110, issue.2, p.1147, 2010.
DOI : 10.1021/cr900184e

F. Nahra, F. Liron, G. Prestat, C. Mealli, A. Messaoudi et al., Striking AcOH Acceleration in Direct Intramolecular Allylic Amination Reactions, Chemistry - A European Journal, vol.105, issue.42, p.11078, 2009.
DOI : 10.1002/chem.200901946

J. Rajabi, M. M. Lorion, V. L. Ly, F. Liron, J. Oble et al., -Catalyzed Aminations, Chemistry - A European Journal, vol.78, issue.6, p.1539, 2014.
DOI : 10.1002/chem.201302744
URL : https://hal.archives-ouvertes.fr/hal-00488634

G. L. Bar, G. C. Lloyd-jones, and K. I. Booker-milburn, Pd(II)-Catalyzed Intermolecular 1,2-Diamination of Conjugated Dienes, Journal of the American Chemical Society, vol.127, issue.20, p.7308, 2005.
DOI : 10.1021/ja051181d

M. E. Cucciolito, A. D. Amora, and A. Vitagliano, Catalytic Coupling of Ethylene and Internal Olefins by Dicationic Palladium(II) and Platinum(II) Complexes:?? Switching from Hydrovinylation to Cyclopropane Ring Formation, Organometallics, vol.24, issue.14, p.3359, 2005.
DOI : 10.1021/om050397l

V. I. Timokhin and S. S. Stahl, Br??nsted Base-Modulated Regioselectivity in the Aerobic Oxidative Amination of Styrene Catalyzed by Palladium, Journal of the American Chemical Society, vol.127, issue.50, p.17888, 2005.
DOI : 10.1021/ja0562806

C. For-allylic, . C. Via-disulfoxide-ligand-see:-c, I. I. Pattillo, P. Strambeanu, N. A. Calleja et al., (2016) and references quoted therein. We assume that the bis-sulfoxide ligand favors the allylic C-H activation step, when this route is permitted. On the other hand, J. Am. Chem. Soc, vol.138, p.1265

C. J. Alexanian, E. J. Lee, and . Sorensen, Palladium-Catalyzed Ring-Forming Aminoacetoxylation of Alkenes, Journal of the American Chemical Society, vol.127, issue.21, p.7690, 2005.
DOI : 10.1021/ja051406k

R. Alam, L. T. Pilarski, E. Pershagen, and K. J. Szabó, However, oxidation taking place via a reversed sequence has also been recently reported, J. Am. Chem. Soc, vol.134, issue.8778, 2012.

G. Poli and G. Giambastiani, An Epiisopicropodophyllin Aza Analogue via Palladium-Catalyzed Pseudo-Domino Cyclization, The Journal of Organic Chemistry, vol.67, issue.26, p.9456, 2002.
DOI : 10.1021/jo026068+

A. Lei and X. Lu, -Tosyl Allylic Amines from Allylic Alcohols and Tosyl Isocyanate via Palladium(II)-Catalyzed Aminopalladation?????-Heteroatom Elimination, Organic Letters, vol.2, issue.15, p.2357, 2000.
DOI : 10.1021/ol006130u
URL : https://hal.archives-ouvertes.fr/in2p3-01158135

J. Dauvergne, A. M. Happe, V. Jadhav, D. Justice, M. Matos et al., Synthesis of 4-azacyclopent-2-enones and 5,5-dialkyl-4-azacyclopent-2-enones, Tetrahedron, vol.60, issue.11, p.2559, 2004.
DOI : 10.1016/j.tet.2004.01.046

A. Joosten, A. K. Persson, R. Millet, M. T. Johnson, and J. Bäckvall, Palladium(II)-Catalyzed Oxidative Cyclization of Allylic Tosylcarbamates: Scope, Derivatization, and Mechanistic Aspects, Chemistry - A European Journal, vol.44, issue.47, p.15151, 2012.
DOI : 10.1002/chem.201202359

A. M. Castro, Claisen Rearrangement over the Past Nine Decades, Chemical Reviews, vol.104, issue.6, p.2939, 2004.
DOI : 10.1021/cr020703u

C. K. Ingold, Structure and Mechanism in Organic Chemistry Brought to you by, pp.457-46347, 1969.